Issue 43, 2023

A perspective on the relative merits/demerits of time-propagators based on Floquet theorem

Abstract

The present report examines the nuances of analytic methods employed in the derivation of evolution operators in periodically driven quantum systems based on Floquet theorem. Specifically, time-propagators of the form, U(t) = P(t)ei[H with combining macron]t defined in the Hilbert space (of finite dimension), are derived through generalized multimodal expansion of the operators involved. While Floquet methods defined in the extended Hilbert space (of infinite dimension) have remained the method of choice for the description of time-evolution at non-stroboscopic time-intervals, the expansion schemes discussed do present an attractive option for similar studies in the standard Hilbert space. Nevertheless, the convergence criteria and suitability of such methods deserve formal validation in problems of experimental relevance. Employing examples comprising periodic Hamiltonians from magnetic resonance spectroscopy, the exactness of Floquet based time-propagators in the Schrödinger and interaction representation is discussed. Through rigorous comparisons between simulations emerging from analytic and exact numerical methods, the relative merits and demerits of different formulations of Floquet based methods are also discussed.

Graphical abstract: A perspective on the relative merits/demerits of time-propagators based on Floquet theorem

Supplementary files

Article information

Article type
Paper
Submitted
09 Aug 2023
Accepted
25 Sep 2023
First published
27 Oct 2023

Phys. Chem. Chem. Phys., 2023,25, 29747-29773

A perspective on the relative merits/demerits of time-propagators based on Floquet theorem

S. Ganguly and R. Ramachandran, Phys. Chem. Chem. Phys., 2023, 25, 29747 DOI: 10.1039/D3CP03801G

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