Facet-dependent Bi2MoO6 for highly efficient photocatalytic selective oxidation of sp3 C–H bonds using O2 as an oxidant

Xiaojing Yang; Xinju Li; Bao Zhang; Taifeng Liu; Zhenpan Chen

doi:10.1039/D3CY00018D

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Facet-dependent Bi₂MoO₆ for highly efficient photocatalytic selective oxidation of sp³ C–H bonds using O₂ as an oxidant†

Xiaojing Yang,

*^a Xinju Li,^b Bao Zhang,^c Taifeng Liu

^d and Zhenpan Chen

*^b

Author affiliations

* Corresponding authors

^a Key Laboratory of Natural Medicine and Immune-Engineering of Henan Province, Henan University, Kaifeng 475004, China
E-mail: xiaojingyang27@163.com

^b School of Chemical Engineering, Xiangtan University, Xiangtan, PR China
E-mail: zpchen@xtu.edu.cn

^c Key Lab for Special Functional Materials, Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, School of Materials Science and Engineering, and Collaborative Innovation Center of Nano Functional Materials and Applications, Henan University, Kaifeng 475004, China

^d National & Local Joint Engineering Research Center for Applied Technology of Hybrid Nanomaterials, Henan University, Kaifeng 475004, China

Abstract

Photocatalytic selective oxidation of sp³ C–H bonds using O₂ is ideal for the hydrocarbons' functionalization. Herein, Bi₂MoO₆ samples with {010} and {001} facets were fabricated by controlling the pH of the solution. Bi₂MoO₆ with exposed {010} facets exhibited 2.3 times greater catalytic activity than that with {001} facets.

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Article information

DOI: https://doi.org/10.1039/D3CY00018D
Article type: Communication
Submitted: 04 Jan 2023
Accepted: 17 Feb 2023
First published: 22 Feb 2023

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Catal. Sci. Technol., 2023,13, 1996-2000

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Facet-dependent Bi₂MoO₆ for highly efficient photocatalytic selective oxidation of sp³ C–H bonds using O₂ as an oxidant

X. Yang, X. Li, B. Zhang, T. Liu and Z. Chen, Catal. Sci. Technol., 2023, 13, 1996 DOI: 10.1039/D3CY00018D

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