Construction of a direct Z-scheme CeO2/UiO-66-NH2 heterojunction for boosting photocatalytic organic pollutant degradation and H2 evolution performance

Abstract

In this study, hollow CeO₂ nanospheres were grown on UIO-66-NH₂ nanosheets to form a novel CeO₂/UiO-66-NH₂ (abbreviation, CU_x) Z-scheme heterojunction photocatalyst by calcination and hydrothermal method for hydrogen production and photocatalytic degradation of organic pollutants. Under visible light, the H₂ generation rate of the CU_0.50 composite was 5662.1 μmol g⁻¹ h⁻¹, which was 22 and 7 fold than that of pure CeO₂ and pure UiO-66-NH₂, respectively. In addition, compared with CeO₂ and UiO-66-NH₂, the as-prepared CU_x composites exhibited enhanced photo-degradation efficiencies for tetracycline (TC) and 2,4-dichlorophenol (DCP) under simulated solar light irradiation. Among them, the CU_0.50 composite demonstrated the highest photocatalytic performance and reached 91.5% for TC, and 94.3% for DCP. In addition, a logical solid-state Z-type electron transfer mechanism is presented with the results of radical scavenging and ESR experiments to illustrate the intensive decomposed ability of the photocatalytic system. The enhanced photocatalytic performance of CU_x heterostructures can be attributed to the formation of a band-position-matched hollow structure heterojunction between CeO₂ and UIO-66-NH₂, which can effectively inhibit the recombination of carriers and increase the specific surface area as well as the light absorption. Moreover, the oxidation and reduction ability of the charge carriers was also increased. This work resulted in a feasible idea for removing organic pollutants and hydrogen production by traditional inorganic semiconductor/MOF-based heterostructured photocatalysts.