Permethylation of the phenylene linker in a cationic ferrocenyl-phenylthioxanthylium dyad increases the amount of the diradical ferrocenium thioxanthyl radical valence tautomer and aids in supressing dimerization of the latter and of the one-electron reduced neutral radical.
M. Nau, L. A. Casper, G. Haug, M. Linseis, S. Demeshko and R. F. Winter, Dalton Trans., 2023, 52, 4674 DOI: 10.1039/D3DT00857F
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