Issue 30, 2023
From the journal:

Dalton Transactions

Spin dynamics in a Heisenberg weak antiferromagnetic chain of an iodide-bridged Cu(ii) complex†

Masanori Wakizaka, ORCID logo *a   Mirosław Arczyński,b   Shraddha Gupta, ORCID logo b   Shinya Takaishib  and  Masahiro Yamashita ORCID logo *bc  

* Corresponding authors

a Frontier Research Institute for Interdisciplinary Sciences, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-Ku, Sendai 980-8578, Japan
E-mail: ma-wakiz@photon.chitose.ac.jp

b Department of Chemistry, Graduate School of Science Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-Ku, Sendai 980-8578, Japan
E-mail: yamasita@agnus.chem.tohoku.ac.jp

c School of Materials Science and Engineering, Nankai University, Tianjin 300350, P. R. China

Abstract

[CuII(chxn)2I]I (chxn = 1R,2R-diaminocyclohexane) has been synthesized, which is the first report of an iodide-bridged Cu(II) chain structure. This chain compound shows S = 1/2 Heisenberg weak antiferromagnetism (J = −0.3 cm−1) and magnetic relaxation (τ = 43 ms at 1.8 K) with a Raman process in a static field.

Graphical abstract: Spin dynamics in a Heisenberg weak antiferromagnetic chain of an iodide-bridged Cu(ii) complex

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Article information

DOI
https://doi.org/10.1039/D3DT01840G
Article type
Communication
Submitted
14 Jun 2023
Accepted
03 Jul 2023
First published
04 Jul 2023

Dalton Trans., 2023,52, 10294-10297

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Spin dynamics in a Heisenberg weak antiferromagnetic chain of an iodide-bridged Cu(II) complex

M. Wakizaka, M. Arczyński, S. Gupta, S. Takaishi and M. Yamashita, Dalton Trans., 2023, 52, 10294 DOI: 10.1039/D3DT01840G

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