Issue 33, 2023

Vanadium-catalysed regioselective hydroboration of epoxides for synthesis of secondary alcohols

Abstract

Regioselective epoxide ring-opening through hydroboration catalysed by a vanadium(III) dialkyl complex supported by a redox-active terpyridine ligand is reported. Secondary alcohols were obtained in high yields via effective Markovnikov hydroboration of terminal epoxides, showcasing a new catalytic application of an earth-abundant vanadium(III) complex.

Graphical abstract: Vanadium-catalysed regioselective hydroboration of epoxides for synthesis of secondary alcohols

Supplementary files

Article information

Article type
Communication
Submitted
15 Jun 2023
Accepted
07 Aug 2023
First published
08 Aug 2023

Dalton Trans., 2023,52, 11395-11400

Author version available

Vanadium-catalysed regioselective hydroboration of epoxides for synthesis of secondary alcohols

G. Zhang, H. Zeng, Q. Tang, S. Ates, S. Zheng and M. C. Neary, Dalton Trans., 2023, 52, 11395 DOI: 10.1039/D3DT01865B

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