Issue 29, 2023

Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses

Abstract

Two new magnesium phosphite-oxalates were prepared under solvent-free conditions using different amines as structure-directing agents. They feature noncentrosymmetric structures with sql and dia topologies, respectively. The two compounds show moderate second-harmonic generation (SHG) responses under 1064 nm laser irradiation. Theoretical calculations were performed to reveal the origin of their SHG responses.

Graphical abstract: Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses

Supplementary files

Article information

Article type
Communication
Submitted
17 Jun 2023
Accepted
05 Jul 2023
First published
07 Jul 2023

Dalton Trans., 2023,52, 9899-9902

Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses

L. Luo, X. Wen, J. Cheng, J. Li, H. Zeng, G. Zou and Z. Lin, Dalton Trans., 2023, 52, 9899 DOI: 10.1039/D3DT01885G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements