Dimeric polybismuth heteroanion of [Rh@Bi10(RhCO)5]2− constructed using Bi10-bowl and square pyramidal Rh@(Rh-CO)5

Yipeng Zang; Yueyue Wang; Ruili Sang; Li Xu

doi:10.1039/D3DT02402D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Dimeric polybismuth heteroanion of [Rh@Bi₁₀(RhCO)₅]²⁻ constructed using Bi₁₀-bowl and square pyramidal Rh@(Rh-CO)₅†

Yipeng Zang,^ab Yueyue Wang,^ab Ruili Sang^a and Li Xu

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: xli@fjirsm.ac.cn

^b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Redox reaction of the monovalent Rh₂(CO)₄Cl₂ and Bi_nⁿ⁻ (n = 2, 3) from K₅Bi₄ in ethylenediamine (en) solution produced the decabismuthide-hexarhodium dianion [Rh@Bi₁₀(RhCO)₅]²⁻ (1a) wherein a novel Bi₁₀-bowl was constructed from oxidized 2Bi₃/2Bi₂ open triangles/dimers, which was stabilized by strong bonding to a reduced Rh@(RhCO)₅ square pyramid. Two 1a dianons are held together by weak interactions (van der Waals forces and spatial resistance) to form a dimer [Rh@Bi₁₀(RhCO)₅]₂⁴⁻ (1). The structure and bonding of the novel polybismuthide heteroanion 1 are discussed.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D3DT02402D
Article type: Paper
Submitted: 27 Jul 2023
Accepted: 25 Sep 2023
First published: 04 Oct 2023

Download Citation

Dalton Trans., 2023,52, 15935-15939

Permissions

Request permissions

Dimeric polybismuth heteroanion of [Rh@Bi₁₀(RhCO)₅]²⁻ constructed using Bi₁₀-bowl and square pyramidal Rh@(Rh-CO)₅

Y. Zang, Y. Wang, R. Sang and L. Xu, Dalton Trans., 2023, 52, 15935 DOI: 10.1039/D3DT02402D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions