Issue 43, 2023
From the journal:

Dalton Transactions

Unusual cleavage of phosphaalkynes triple bond in the coordination sphere of transition metals†

Mehdi Elsayed Moussa,‡a   Eva-Maria Rummel,‡a   Maria Eckhardt,a   Christoph Riesingera  and  Manfred Scheer ORCID logo *a  

* Corresponding authors

a Department of Inorganic Chemistry, University of Regensburg, D-93040 Regensburg, Germany
E-mail: manfred.scheer@ur.de

Abstract

The reaction of RC[triple bond, length as m-dash]P (R = Me, tBu, iPr) with Co2(CO)8 and Fe2(CO)9 under mild conditions led to unpredictable fragmentations of the C[triple bond, length as m-dash]P triple bond and subsequent formation of clusters with a dimeric Co3E (E = P and RC) and an Fe3P(CR) core, respectively.

Graphical abstract: Unusual cleavage of phosphaalkynes triple bond in the coordination sphere of transition metals

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Article information

DOI
https://doi.org/10.1039/D3DT02472E
Article type
Communication
Submitted
01 Aug 2023
Accepted
10 Oct 2023
First published
11 Oct 2023

Dalton Trans., 2023,52, 15656-15659

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Unusual cleavage of phosphaalkynes triple bond in the coordination sphere of transition metals

M. Elsayed Moussa, E. Rummel, M. Eckhardt, C. Riesinger and M. Scheer, Dalton Trans., 2023, 52, 15656 DOI: 10.1039/D3DT02472E

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