Photoinduced large magnetic change at room temperature and radical-quenched spin glass in a cyanide-bridged MnII–FeIII compound

Abstract

By the coordination assembly of a redox photoactive functional motif and a cyanide-bridged moiety, a cyanide-bridged Mn^II–Fe^III compound with large photoinduced magnetic change at room-temperature due to photoinduced electron transfer was obtanied. This compound also shows unprecedented radical-quenched spin glass in molecule based magnets.