Issue 22, 2023

Enantiopure natural deep eutectic solvents for metal–organic framework chiral induction

Abstract

A green alternative approach to the chiral induction of a metal–organic framework (MOF) has been explored using the natural deep eutectic solvents (DES) proline : thymol (1 : 7) and menthol : thymol (1 : 1). These solvents have been successfully employed for the preparation of the MIL-103 MOF and lead to an enantioenrichment of the porous material when used in enantiopure form, as demonstrated by circular dichroism.

Graphical abstract: Enantiopure natural deep eutectic solvents for metal–organic framework chiral induction

Supplementary files

Article information

Article type
Communication
Submitted
10 Aug 2023
Accepted
17 Oct 2023
First published
18 Oct 2023
This article is Open Access
Creative Commons BY-NC license

Green Chem., 2023,25, 9103-9108

Enantiopure natural deep eutectic solvents for metal–organic framework chiral induction

R. A. Maia, A. Fluck, C. Maxim, B. Louis and S. A. Baudron, Green Chem., 2023, 25, 9103 DOI: 10.1039/D3GC02993J

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