Single-particle dispersion of carbon dots in the nano-hydroxyapatite lattice achieving solid-state green fluorescence

Abstract

Carbon dots (CDs), as new carbon nanomaterials, have potential applications in multiple fields due to their superior optical properties, good biocompatibility, and easy preparation. However, CDs are typically an aggregation-caused quenching (ACQ) material, which has a huge limitation on the practical application of CDs. To solve this problem, in this paper, CDs were prepared by the solvothermal method using citric acid and o-phenylenediamine as precursors and dimethylformamide as solvent. Then using CDs as nucleating agents, solid-state green fluorescent CDs were synthesized by in situ growth of nano-hydroxyapatite (HA) crystals on the surface of CDs. The results show that CDs are stably dispersed single-particlely in the form of bulk defects in the nano-HA lattice matrices with a dispersion concentration of 3.10%, and solid-state green fluorescence of CDs is achieved with a stable emission wavelength peak position near 503 nm, which provides a new solution to the ACQ problem. CDs-HA nanopowders were further used as LED phosphors to obtain bright green LEDs. In addition, CDs-HA nanopowders showed excellent performance in cell imaging (mBMSCs and 143B) applications, which provides a new scheme for further applications of CDs in the field of cell imaging and even in vivo imaging.