Facile synthesis of water-soluble silver nanoclusters for the photocatalytic degradation of dyes by multivariate optimization approach

Abstract

In this study, silver nanoclusters protected by the natural tripeptide ligand (GSH@Ag NCs) were constructed for photocatalytic dye degradation. The ultrasmall GSH@Ag NCs were found to exhibit a remarkably high degradation capability. Aqueous solutions of the hazardous organic dye Erythrosine B (Ery. B) and Rhodamine B (Rh. B) were subjected to degradation in the presence of Ag NCs under solar light and white-light LED irradiation. The degradation efficiency of GSH@Ag NCs was evaluated using UV-vis spectroscopy, where Erythrosine B showed considerably high degradation of 94.6% compared to Rhodamine B, which was degraded by 85.1%, corresponding to a 20 mg L⁻¹ degradation capacity in 30 min respectively under solar exposure. Moreover, the degradation efficacy for the above-mentioned dyes demonstrated a dwindling trend under white-light LED irradiation, attaining 78.57 and 67.923% degradation under the same experimental conditions. The astoundingly high degradation efficiency of GSH@Ag NCs under solar-light irradiation was due to the high I of 1370 W for solar light versus 0.07 W for LED light, along with the formation of hydroxyl radicals HO˙ on the catalyst surface initiating degradation due to oxidation.