Defect-rich Mo2S3 loaded wood-derived carbon acts as a spacer in lithium–sulfur batteries: forming a polysulfide capture net and promoting fast lithium flux

Abstract

Due to the sluggish kinetics of sulfur conversion and the large volume change of the lithium anode, along with the formation of lithium dendrites, lithium–sulfur batteries (LSBs) usually exhibit severe capacity decay and poor cycle life. It is necessary to consider the factors associated with cathodes, separators and anodes in an integrated manner to solve the problems existing in LSBs. In this paper, a vertically aligned porous carbon decorated with transition metal sulfides was introduced between a cathode and an anode to comprehensively solve the problems of LSBs. Widely existing natural wood was used as the framework structure, and Mo₂S₃ with abundant sulfur vacancies was deposited into its channels. Theoretical calculations and experimental results have confirmed a low energy barrier for sulfur conversion and the presence of a strong electric field around the spacer, which benefits fast ion transportation. As a result, on employing the multifunctional spacer, LSB full cells delivered a high initial capacity and a long cycle life. This study provides a reference for reducing development cost, simplifying optimization steps and promoting the commercial application of LSBs.