Dissociative reactions of [Au25(SR)18]− at copper oxide nanoparticles and formation of aggregated nanostructures

Abstract

Reactions between nanoclusters (NCs) have been studied widely in the recent past, but such processes between NCs and metal–oxide nanoparticles (NPs), belonging to two different size ranges, have not been explored earlier. For the first time, we demonstrate the spontaneous reactions between an atomically precise NC, [Au₂₅(PET)₁₈]⁻ (PET = 2-phenylethanethiolate), and polydispersed copper oxide nanoparticles with an average diameter of 50 nm under ambient conditions. These interparticle reactions result in the formation of alloy NCs and copper-doped NC fragments, which assemble to form nanospheres at the end of the reaction. High-resolution electrospray ionization mass spectrometry (ESI MS), transmission electron microscopy (HR-TEM), electron tomography, and X-ray photoelectron spectroscopy (XPS) studies were performed to understand the structures formed. The results from our study show that interparticle reactions can be extended to a range of chemical systems, leading to diverse alloy NCs and self-assembled colloidal superstructures.