CdTe magic-size cluster synthesis via a cation exchange method and conversion mechanism

Abstract

The quasi-metallic nature of Te is not conducive to telluride formation and crystallization, which makes the synthesis of CdTe magic-size clusters (MSCs) in a single-ensemble form still challenging. CdTe MSCs are usually synthesized by direct synthesis, a method that must avoid the formation of quantum dots by selecting suitable active precursors and precisely controlling the reaction temperature. In addition, the organic Cd compounds and superhydrogenated precursors used are air-sensitive. Herein, CdTe MSC-448 in a single-ensemble form was synthesized for the first time via a cation exchange method using ZnTe MSC-389 as a template and Cd²⁺ as an exchange ion. In situ absorption spectroscopy characterization combined with the two-pathway model proposed by Yu's group reveals that the conversion of ZnTe MSC-389 into CdTe MSC-448 is assisted by their corresponding precursor compounds (PCs). After the addition of Cd precursors to ZnTe MSC-389 solution, ZnTe MSC-389 is transformed into ZnTe PC-389, which then undergoes a rapid cation exchange reaction with Cd²⁺ to yield CdTe PC-448, and CdTe PC-448 is finally converted into CdTe MSC-448. CdTe MSCs in single-ensemble form were obtained by cation exchange in air at room temperature, avoiding the formation of quantum dots (QDs) at high temperatures in the direct synthesis method conducted without the use of toxic and expensive active precursors, which provides a new route to the synthesis of CdTe MSCs.