Issue 12, 2023

Stereoselective synthesis of five- and six-membered carbocycles via Matteson homologation/ring closing metathesis

Abstract

The Matteson homologation is found to be a versatile tool for the stereoselective synthesis of polyunsaturated alkyl boronic esters, which are excellent precursors for the construction of five- and six-membered carbocycles via ring-closing metathesis. The high diversity of the Matteson reaction allows for the preparation of highly substituted cyclic boronic esters, which are also suitable for further homologations.

Graphical abstract: Stereoselective synthesis of five- and six-membered carbocycles via Matteson homologation/ring closing metathesis

Supplementary files

Article information

Article type
Research Article
Submitted
28 Mar 2023
Accepted
09 May 2023
First published
16 May 2023
This article is Open Access
Creative Commons BY-NC license

Org. Chem. Front., 2023,10, 2963-2967

Stereoselective synthesis of five- and six-membered carbocycles via Matteson homologation/ring closing metathesis

T. Kinsinger and U. Kazmaier, Org. Chem. Front., 2023, 10, 2963 DOI: 10.1039/D3QO00457K

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