Preparation and self-assembly of ionic (PNIPAM-co-VIM) microgels and their adsorption property for phosphate ions

Abstract

Using N-isopropyl acrylamide (NIPAM) as the main monomer, 1-vinyl imidazole (VIM) containing tertiary amine groups as the functional comonomer, and 1,5-dibromo pentane as the crosslinking agent, ionic P(NIPAM-co-VIM) microgels were prepared by a two-step method. The crosslinking agent was reacted with tertiary amino groups by the quaternary amination. The results of zeta potential and particle size analysis showed that P(NIPAM-co-VIM) microgels were positively charged and had a particle size of about 400 nm, and the microgels with 11 wt% VIM still showed temperature sensitivity with a volume phase transition temperature of approximately 37.5 °C. The effects of VIM content, ambient temperature, and pH on the adsorption properties of the microgels for phosphate anions were explored. The self-assembly of the positively charged P(NIPAM-co-VIM) microgels with polyelectrolytes and the adsorption behavior of the layers for phosphate anions were studied using a quartz crystal microbalance (QCM). It was found that at a phosphate concentration of 0.3 mg mL⁻¹, VIM mass fraction of 11%, pH of 5, and temperature of 20 °C, the largest adsorption capacity of P(NIPAM-co-VIM) microgel on phosphate ions could reach 346.3 mg g⁻¹. The frequency responses of the microgel-modified QCM sensor could reach 3.0, 18.8, and 25.9 Hz when exposed to 10⁻⁸, 10⁻⁷, and 10⁻⁶ M phosphate solutions. Therefore, the ionic (PNIPAM-co-VIM) microgels could be promising for fabricating anion-binding materials for separation and sensing applications.