Catalytic performance of PVP-coated CuO nanosheets under environmentally friendly conditions

Abstract

Aromatic nitro compounds are an increasing concern worldwide due to their potential toxicity, prompting a quest for efficient removal approaches. This study established a simple and environmentally friendly method to synthesize a highly efficient, recoverable and stable CuO nanosheets catalyst to overcome public health and environmental problems caused by nitro aromatic compounds. In the current research, the effect of different concentrations of copper nitrate on the size and shape of CuO nanostructures in the chemical synthesis was studied. The CuO nanosheets were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR) and ultraviolet-visible spectrophotometry. It was found that at concentrations of 0.07 M and 0.1 M of copper nitrate, pure CuO was formed. The FTIR results showed that carbonyl group in PVP coordinated with CuO and formed a protective layer. The as-synthesized CuO nanosheets with an average width of 60 ± 23 nm and length of 579 ± 154 were used as a catalyst for highly selective and efficient reduction of aromatic nitro and aromatic carboxylic acid to the corresponding amine and alcohol compounds. The reduction reaction was monitored by either UV-Vis absorption spectroscopy or high performance liquid chromatography (HPLC). 4-Nitrophenol and 4-nitroaniline were reduced to corresponding amine compounds within 12 min and 6 min, respectively in the presence of a reasonable amount of catalyst and reducing agent. The CuO nanosheets also exhibited excellent stability. The catalyst can be reused without loss of its activity after ten runs.