Issue 8, 2023

Synthesis of neodymium ferrite incorporated graphitic carbonitride (NdFe2O4@g-C3N4) and its application in the photodegradation of ciprofloxacin and ampicillin in a water system

Abstract

Purification of antibiotic-contaminated drinking water sources is faced with limitations. Therefore, this study incorporated neodymium ferrite (NdFe2O4) in graphitic carbonitride (g-C3N4) to form NdFe2O4@g-C3N4 as a photocatalyst for removing ciprofloxacin (CIP) and ampicillin (AMP) from aqueous systems. X-ray diffraction (XRD) revealed a crystallite size of 25.15 nm for NdFe2O4 and 28.49 nm for NdFe2O4@g-C3N4. The bandgap is 2.10 and 1.98 eV for NdFe2O4 and NdFe2O4@g-C3N4, respectively. The transmission electron micrograph (TEM) images of NdFe2O4 and NdFe2O4@g-C3N4 gave an average particle size of 14.10 nm and 18.23 nm, respectively. Scanning electron micrograph (SEM) images showed heterogeneous surfaces with irregular-sized particles suggesting agglomeration at the surfaces. NdFe2O4@g-C3N4 (100.00 ± 0.00% for CIP and 96.80 ± 0.80% for AMP) exhibited better photodegradation efficiency towards CIP and AMP than NdFe2O4 (78.45 ± 0.80% for CIP and 68.25 ± 0.60% for AMP) in a process described by pseudo-first-order kinetics. NdFe2O4@g-C3N4 showed a stable regeneration capacity towards degradation of CIP and AMP with a capacity that is above 95% even at the 15th cycle of treatment. The use of NdFe2O4@g-C3N4 in this study revealed its potential as a promising photocatalyst for removing CIP and AMP in water systems.

Graphical abstract: Synthesis of neodymium ferrite incorporated graphitic carbonitride (NdFe2O4@g-C3N4) and its application in the photodegradation of ciprofloxacin and ampicillin in a water system

Article information

Article type
Paper
Submitted
18 Dec 2022
Accepted
07 Feb 2023
First published
13 Feb 2023
This article is Open Access
Creative Commons BY license

RSC Adv., 2023,13, 5405-5418

Synthesis of neodymium ferrite incorporated graphitic carbonitride (NdFe2O4@g-C3N4) and its application in the photodegradation of ciprofloxacin and ampicillin in a water system

A. Adewuyi and R. A. Oderinde, RSC Adv., 2023, 13, 5405 DOI: 10.1039/D2RA08070B

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements