Fabrication and characterization of a flexible and disposable impedance-type humidity sensor based on polyaniline (PAni)

Abstract

This work presents a highly sensitive, economical, flexible, and disposable humidity sensor developed with a facile fabrication process. The sensor was fabricated on cellulose paper using polyemaraldine salt, a form of polyaniline (PAni), via the drop coating method. A three-electrode configuration was employed to ensure high accuracy and precision. The PAni film was characterized using various techniques including ultraviolet-visible (UV-vis) absorption spectroscopy, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The humidity sensing properties were evaluated through electrochemical impedance spectroscopy (EIS) in a controlled environment. The sensor exhibits a linear response with R² = 0.990 for impedance over a wide range of (0%–97%) relative humidity (RH). Further, it displayed consistent responsiveness, a sensitivity of 1.1701 Ω/%RH, acceptable response (≤220 s)/recovery (≤150 s), excellent repeatability, low hysteresis (≤2.1%) and long-term stability at room temperature. The temperature dependence of the sensing material was also studied. Due to its unique features, cellulose paper was found to be an effective alternative to conventional sensor substrates according to several factors including compatibility with the PAni layer, flexibility and low cost. These unique characteristics make this sensor a promising option for use in specific healthcare monitoring, research activities, and industrial settings as a flexible and disposable humidity measurement tool.