Efficient CuO/Ag2WO4 photoelectrodes for photoelectrochemical water splitting using solar visible radiation

Abstract

Water splitting energy production relies heavily on the development of high-performance photoelectrochemical cells (PECs). Among the most highly regarded semiconductor materials, cupric oxide (CuO) is an excellent photocathode material. Pristine CuO does not perform well as a photocathode due to its tendency to recombine electrons and holes rapidly. Photocathodes with high efficiency can be produced by developing CuO-based composite systems. The aim of our research is to develop an Ag₂WO₄/CuO composite by incorporating silver tungstate (Ag₂WO₄) nanoparticles onto hydrothermally grown CuO nanoleaves (NLs) by successive ionic layer adsorption and reaction (SILAR). To prepare CuO/Ag₂WO₄ composites, SILAR was used in conjunction with different Ag₂WO₄ nanoparticle deposition cycles. Physicochemical characterization reveals well-defined nanoleaves morphologies with tailored surface compositions. Composite CuO/Ag₂WO₄ crystal structures are governed by the monoclinic phase of CuO and the hexagonal phase of Ag₂WO₄. It has been demonstrated that the CuO/Ag₂WO₄ composite has outstanding performance in the PEC water splitting process when used with five cycles. In the CuO/Ag₂WO₄ photocathode, water splitting activity is observed at low overpotential and high photocurrent density, indicating that the reaction takes place at low energy barriers. Several factors contribute to PEC performance in composites. These factors include the high density of surface active sites, the high charge separation rate, the presence of favourable surface defects, and the synergy of CuO and Ag₂WO₄ photoreaction. By using SILAR, silver tungstate can be deposited onto semiconducting materials with strong visible absorption, enabling the development of energy-efficient photocathodes.