Leaching of phosphate ores with lower dissolution of metallic impurities: the dual role of sodium oleate

Abstract

In this work, we report the use of surfactants to improve the performance of phosphate ore leaching while reducing the concentration of metallic impurities in the leaching solution. Based on the zeta potential analysis, sodium oleate (SOL) is determined as a suitable surfactant because it can change interfacial properties and improve ionic diffusion. This is experimentally demonstrated by the high leaching performance. After that, the reaction conditions on the leaching performance are systematically investigated. Under the optimal experimental conditions (SOL concentration of 10 mg L⁻¹, sulfuric acid concentration of 1.72 mol L⁻¹, leaching temperature of 75 °C, and leaching time of 180 min), a high phosphorus leaching efficiency of 99.51% is achieved. Meanwhile, the leaching solution presents a lower content of metallic impurities. Further measurements performed on the leaching residues indicate that the additive SOL can promote the growth of platy crystals and facilitate PO leaching. Overall, this work demonstrates that the SOL-assisted leaching method allows for highly-efficient utilization of PO and high-purity phosphoric acid production.