A facile strategy of using MoS2 quantum dots for fluorescence-based targeted detection of nitrobenzene

Abstract

We present a simple approach for producing photoluminescent MoS₂ quantum dots (QDs) using commercial MoS₂ powder as a precursor along with NaOH and isopropanol. The synthesis method is particularly easy and environmentally friendly. The successful intercalation of Na⁺ ions into MoS₂ layers and subsequent oxidative cutting reaction leads to the formation of luminescent MoS₂ QDs. The present work, for the first time, shows the formation of MoS₂ QDs without any additional energy source. The as-synthesized MoS₂ QDs were characterized using microscopy and spectroscopy. The QDs have a few layer thicknesses and a narrow size distribution with an average diameter of ∼3.8 nm. Nitrobenzene (NB), an industrial chemical, is both toxic to human health and dangerously explosive. The present MoS₂ QDs can be used as an effective photoluminescent probe, and a new turn-off sensor for NB detection. The selective quenching was operated via multiple mechanisms; electron transfer between the nitro group and MoS₂ QDs through dynamic quenching and the primary inner filter effect (IFE). The quenching has a linear relationship with NB concentrations from 0.5 μM to 11 μM, with a calculated detection limit of 50 nM.