Composite beads from chitosan and zeolitic imidazolate framework-8 for the adsorption and photocatalytic degradation of reactive red 141

Abstract

This study describes the fabrication of composite beads comprising chitosan and zeolitic imidazolate framework-8 (ZIF-8) as a natural biodegradable dye adsorbent and support for ZnO photocatalyst. Chitosan beads were cross-linked with trisodium citrate dihydrate to enhance the adsorption capacity for the reactive red 141 dye (RR141). The ability was further improved by adding ZIF-8. The optimum loading was 2.5%, and the adsorption equilibrium was reached within 2 h. The maximum adsorption capacity of the composite beads was 6.51 mg g⁻¹ at pH 4 when an initial concentration of 1000 mg L⁻¹ was used. The pseudo-second-order kinetics model and the Langmuir isotherm model best described the adsorption process. The composite beads could also adsorb dyes like reactive black, Congo red, direct yellow, reactive orange, rhodamine B, crystal violet, and methylene blue (MB). Thermal stability was significantly improved after coating the surface of the 2.5% ZIF beads with a ZnO photocatalyst. After UV irradiation for 5 h, the photocatalytic beads containing 2.59 weight percent of ZnO could decolorize 99% of MB and 90% of RR141 dyes with a degradation rate of 0.6032 h⁻¹ and 0.3198 h⁻¹, respectively. Furthermore, the photocatalytic beads remained effective for at least ten consecutive cycles.