Light and pH dual-responsive spiropyran-based cellulose nanocrystals

Abstract

Reversibly light and pH dual-responsive spiropyran-based cellulose nanocrystals (SP-CNCs) is synthesized by the attachment of carboxyl-containing spiropyran (SP-COOH) onto cellulose nanocrystals (CNCs). The resulting structure and properties of SP-CNCs are examined by Fourier transform infrared spectroscopy (FT-IR), elemental analysis, transmission electron microscopy (TEM), atomic force microscopy (AFM), dynamic laser light scattering (DSL), ζ-potential measurements and ultraviolet-visible (UV-Vis) light absorption spectroscopy. SP-CNCs exhibit excellent photochromic and photoswitching properties. Spiropyran moieties on SP-CNCs can be switched between open-ring merocyanine (MC) and closed ring spiropyran (SP) forms under UV/Vis irradiation, leading to color changes. Moreover, SP-CNCs display improved photoresponsiveness, photoreversibility, fatigue resistance, and stability in DMSO than in H₂O. We further investigate the pH-responsive behavior of SP-CNCs in H₂O. SP-CNCs aqueous solution display different colors at different pH values, which can be directly observed by naked eye, indicating that SP-CNCs can function as a visual pH sensor. These results suggest that light and pH dual-responsive SP-CNCs possess great potential for applications in reversible data storage, sensing, optical switching and light-controlled nanomaterials.