Flower ball cathode assembled from Cu doped Co3S4/Ni3S2 ultrathin nanosheets in a photocatalytic fuel cell for efficient photoelectrochemical rifampicin purification and simultaneous electricity generation based on a CuO QDs/TiO2/WO3 photoanode

Abstract

Herein, an efficient CuO QDs/TiO₂/WO₃ photoanode and a Cu doped Co₃S₄/Ni₃S₂ cathode were successfully synthesized. The optimized CuO QDs/TiO₂/WO₃ photoanode achieved a photocurrent density of 1.93 mA cm⁻² at 1.23 vs. RHE, which was 2.27 times that of a WO₃ photoanode. The CuO QDs/TiO₂/WO₃-buried junction silicon (BJS) photoanode was coupled with the Cu doped Co₃S₄/Ni₃S₂ cathode to construct a novel photocatalytic fuel cell (PFC) system. The as-established PFC system showed a high rifampicin (RFP) removal ratio of 93.4% after 90 min and maximum power output of 0.50 mW cm⁻². Quenching tests and EPR spectra demonstrated that ˙OH, ˙O₂⁻ and ¹O₂ were the main reactive oxygen species in the system. This work provides a possibility to construct a more efficient PFC system for environmental protection and energy recovery in the future.