Fabrication of novel strain sensors from green TPV nanocomposites based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV)/silicone rubber/silicon-modified graphene oxide

Abstract

In this study, a new thermoplastic vulcanizate (TPV) blend of silicone rubber (SR) and poly (3-hydroxybutyrate-co-3-hydroxy valerate) (PHBV) including silicon-modified graphene oxide (SMGO), is used to fabricate highly flexible and sensitive strain sensors. The sensors are built with an extremely low percolation threshold of 1.3 vol%. We investigated the effect of adding SMGO nanoparticles to strain-sensing applications. The findings demonstrated that increasing the SMGO concentration enhanced the composite's mechanical, rheological, morphological, dynamic mechanical, electrical, and strain-sensing capabilities. But too many SMGO particles can reduce elasticity and cause nanoparticle aggregation. The nanocomposite's gauge factor (GF) values were discovered to be 375, 163, and 38, with nanofiller contents of 5.0 wt%, 3.0 wt%, and 1.0 wt% respectively. Cyclic strain-sensing behavior showed their ability to recognize and classify various motions. Due to its superior strain-sensing capabilities, TPV5 was chosen to assess the repeatability and stability of this material when utilized as a strain sensor. The sensor's excellent stretchability, sensitivity (GF = 375), and remarkable repeatability during cyclic tensile testing allowed them to be stretched beyond 100% of the applied strain. This study offers a new and valuable method for building conductive networks in polymer composites, with potential uses in strain sensing, especially in biomedical applications. The study also emphasizes the potential of SMGO as a conductive filler for developing extremely sensitive and flexible TPEs with enhanced, environmentally friendly features.