Enhanced electrocatalytic oxygen redox reactions of iron oxide nanorod films by combining oxygen vacancy formation and cobalt doping

Abstract

A synergistic effect of Co-doping and vacuum-annealing on electrochemical redox reactions of iron oxide films is demonstrated in the present work. In this research, a series of defect-rich iron oxy/hydroxide nanorod arrays: α-FeOOH, Fe₂O₃, and FeO_x nanorod thin film catalysts were synthesized via a hydrothermal approach followed by thermal and vacuum treatments. Besides, a cobalt doping process was employed to prepare the thin film of Co-doped FeO_x nanorods. The morphology, crystallinity, and electrochemical activities of Co-doped oxygen-deficient FeO_x (Co-FeO_x/FTO) show strong correlations with metal concentration and thermal treatments. The electrochemical measurements demonstrated that the as-deposited Co-doped FeO_x NR catalyst could achieve a maximum OER current of 30 mA cm⁻², which was six times greater than that recorded by as-deposited Co-doped FeOOH NR catalysts (5.7 mA cm⁻²) at 1.65 V vs. RHE, confirming the superior electrocatalytic OER activity at the as-deposited Co-doped FeO_x NR catalyst after cobalt doping. It is believed that these results are attributed to two factors: the synergistic effect of Co doping and the defect-rich nature of FeO_x nanorod catalysts that are used in sustainable energy systems.