Semiquantitative and visual detection of ferric ions in real samples using a fluorescent paper-based analytical device constructed with green emitting carbon dots

Abstract

A simple and portable paper-based analytical device was developed for visual and semiquantitative detection of ferric ion in real samples using green emitting carbon dots (CDs), which were prepared via microwave method using sodium citrate, urea and sodium hydroxide as raw materials and then loaded on the surface of paper substrate. When Fe³⁺ exists, the green fluorescence of CDs was quenched and significant color change from green to dark blue were observed, resulting the visual detection of Fe³⁺ with a minimum distinguishable concentration of 100 μM. By analyzing the intensity changes of green channels of test paper with the help of smartphone, the semiquantitative detection was realized within the range of 100 μM to 1200 μM. The proposed paper-based analytical devices have great application prospects in on site detection of Fe³⁺ in real samples.