Issue 47, 2023, Issue in Progress

Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides

Abstract

A simple approach for copper-promoted S-arylation reactions utilizing triarylbismuths or triarylantimonys as arylating reagents has been described. These reactions can be performed under mild conditions and exhibit remarkable functional group tolerance and chemoselectivity. The corresponding 2-arylthiopyridine 1-oxide derivatives and arylthioanilines/phenols have been successfully synthesized, achieving good to excellent yields across over 49 examples.

Graphical abstract: Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides

Supplementary files

Article information

Article type
Paper
Submitted
27 Sep 2023
Accepted
06 Nov 2023
First published
10 Nov 2023
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2023,13, 33167-33174

Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides

M. Nie, X. Zhou, J. Tang, D. Huang, X. Xiao and J. Xie, RSC Adv., 2023, 13, 33167 DOI: 10.1039/D3RA06582K

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