Issue 36, 2023

Efficient faradaic supercapacitor energy storage using redox-active pyrene- and benzodithiophene-4,8-dione-tethered conjugated microporous polymers

Abstract

Conjugated microporous polymers (CMPs) are intriguing options for a wide range of applications; however, CMP-tethered energy storage devices such as supercapacitors have received relatively little investigation due to limitations in energy density, electronic conductivity, electrochemical/structural durability, and specific capacitance. We present here the synthesis of a unique sort of redox-active conjugated microporous polymers, Py-BDT and Py-Ph-BDT CMPs, based on pyrene (Py) and redox-active benzo[1,2-b:4,5-b′]dithiophene-4-dione (BDT) units as efficient and stable electrode components for supercapacitor energy storage devices. The CMPs exhibited outstanding thermal stabilities (Td10: approximately 564 °C; char yield: approximately 70.5%) and surface areas (around 427 m2 g−1). Intriguingly, integrating the pyrene and redox-active BDT units into the CMP core leads to rapid charge transport, outstanding faradaic energy storage, and remarkable conductivity. As expected, the resulting CMPs show an excellent three-electrode capacitance of 712 F g−1 at 0.5 A g−1 current density, which is a better specific capacity than that of the previously reported conventional CMPs. A symmetric two-electrode supercapacitor constructed with the Py-Ph-BDT CMP displays an effective capacitance of 429 F g−1 and an energy density of 38.21 W h kg−1 at a potential of 0.8 V and maintains 80% of its beginning capacitance over 4000 cycles. Our research provides a simple route to combine various electroactive moieties with redox-active benzodithiophene-4,8-dione to develop outstanding supercapacitors.

Graphical abstract: Efficient faradaic supercapacitor energy storage using redox-active pyrene- and benzodithiophene-4,8-dione-tethered conjugated microporous polymers

Supplementary files

Article information

Article type
Paper
Submitted
30 May 2023
Accepted
10 Aug 2023
First published
12 Aug 2023

J. Mater. Chem. A, 2023,11, 19408-19417

Efficient faradaic supercapacitor energy storage using redox-active pyrene- and benzodithiophene-4,8-dione-tethered conjugated microporous polymers

T. A. Gaber, L. R. Ahmed and A. F. M. EL-Mahdy, J. Mater. Chem. A, 2023, 11, 19408 DOI: 10.1039/D3TA03198E

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