Issue 33, 2023

CoZnO/C@BCN nanocomposites derived from bimetallic hybrid ZIFs for enhanced electromagnetic wave absorption

Abstract

Rational design of dielectric–magnetic integrated nanomaterials for meeting impedance matching has been a significant challenge in the field of electromagnetic wave (EMW) absorption. Here, novel zeolitic imidazolate framework (ZIF) derivative-based carbon materials with a rational structure derived from ZIF-L(Zn)/ZIF-L(Co) are prepared to enhance the EMW absorption performance by simple mixing and pyrolysis. Tuning the molar ratio of ZIF-L(Zn) and ZIF-L(Co) can effectively alter the magnetic loss of the CoZnO/C@BCN composite. The metal particles embedded in the boron nitride nanotubes (BCNs) after ZIF-L(Zn) and ZIF-L(Co) pyrolysis reduce the dielectric coefficient, promote effective dispersion of metal particles, and regulate impedance matching. As a result, the CoZnO/C@BCN composite displays excellent EMW absorption with a minimum reflection loss (RL) of −54.9 dB at 6.5 GHz, as well as an effective absorption bandwidth (EAB) of 5.2 GHz (from 12.72 GHz to 17.92 GHz) with an equal absorber thickness of 1.9 mm. The CoZnO/C@BCNs achieve an excellent EMW absorption capacity, which is attributed to the multiple loss mechanisms and outstanding impedance matching. The results provide new insight into MOF-based carbon absorbers with light weight and high performance, which demonstrate significant potential in the treatment of EMW absorption.

Graphical abstract: CoZnO/C@BCN nanocomposites derived from bimetallic hybrid ZIFs for enhanced electromagnetic wave absorption

Supplementary files

Article information

Article type
Paper
Submitted
02 Jun 2023
Accepted
27 Jul 2023
First published
28 Jul 2023

J. Mater. Chem. A, 2023,11, 17737-17747

CoZnO/C@BCN nanocomposites derived from bimetallic hybrid ZIFs for enhanced electromagnetic wave absorption

X. Lin, J. Hong, C. Wang, M. Su and S. Zhou, J. Mater. Chem. A, 2023, 11, 17737 DOI: 10.1039/D3TA03286H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements