High performance and self-powered photodetectors based on Se/CsPbBr3 heterojunctions

Abstract

The inorganic perovskite CsPbBr₃ has attracted much attention in photodetector fabrication. In this paper, Se/CsPbBr₃ heterojunctions were prepared by a spin coating method by combining highly crystallized p-type Se microtubes (Se-MTs) and n-type CsPbBr₃ nanoparticles. Se-MTs were deposited by chemical vapor deposition at a relatively low temperature of 330 °C. CsPbBr₃ nanoparticles can enhance light absorption in the wavelength range of 350–550 nm, improving the optical response of p–n Se/CsPbBr₃ junctions. The Se/CsPbBr₃ heterojunction photodetectors exhibit excellent self-powered characteristics and a broadband spectral response range of 368–800 nm. Especially, under an illumination of 550 nm under zero bias voltage, Se/CsPbBr₃ detectors exhibit maximum responsivity (47.6 mA W⁻¹, 436% higher than that of pure Se-MT at 0.1 V), the highest specific detectivity of 4.9 × 10¹⁰ Jones (two times higher than Se-MT at 0.1 V), a high on/off ratio of 235, and fast response speed (18/40 ms). Therefore, the low-cost and high responsivity make this device quite promising in broadband high-performance devices with self-powered detection.