Issue 11, 2023

Design and analysis of a SnS2/WS2/V2O5 double-heterojunction toward high-performance photovoltaics

Abstract

Tungsten disulfide (WS2) transition metal dichalcogenide (TMDC) absorber-based solar cells comprising tin disulfide (SnS2) buffer and vanadium (V) oxide V2O5 back surface field (BSF) layers have been designed and analyzed using a SCAPS-1D simulator in this study. The initial experimentation on back metal contact (BMC) and front metal contact (FMC) optimization involved the use of different materials to obtain the least resistive junction at the semiconductor–metal (M–S) interface, where the best potential was found. Following an extensive investigation nickel (Ni) and aluminum (Al) is determined to be the optimal material for the back and front contact, respectively. Subsequently, the impact of major parameters which affecting the photovoltaic (PV) performance, such as absorber layer thickness, doping concentration, bulk defect density, interface defect density, operating temperature, and surface recombination velocity, were studied systematically. An improved photoconversion efficiency (PCE) of over 32% (around 9% higher) was obtained with the open-circuit voltage (VOC) of 1.1 V, short-circuit current (JSC) of 37.2 mA cm−2, and fill factor (FF) of 84% with the Al/FTO/SnS2/WS2/V2O5/Ni heterostructure, compared to 23.4%, 0.89 V, 31.2 mA cm−2 and 81% for the pristine cell (without V2O5 BSF). These outcomes obtained from comprehensive studies reveal the huge potential of the SnS2/WS2/V2O5 double-heterostructure to be applied as a PV cell and pave a resourceful pathway for the experimental fabrication of WS2-TMDC absorber-based high-performance photonic devices.

Graphical abstract: Design and analysis of a SnS2/WS2/V2O5 double-heterojunction toward high-performance photovoltaics

Article information

Article type
Paper
Submitted
25 May 2023
Accepted
08 Sep 2023
First published
08 Sep 2023
This article is Open Access
Creative Commons BY license

Energy Adv., 2023,2, 1843-1858

Design and analysis of a SnS2/WS2/V2O5 double-heterojunction toward high-performance photovoltaics

J. Al Mahmud, Md. F. Rahman, A. Kuddus, Md. H. Ali, A. T. M. S. Islam, Md. D. Haque, S. R. A. Ahmed, M. Mushtaq and A. B. Md. Ismail, Energy Adv., 2023, 2, 1843 DOI: 10.1039/D3YA00231D

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