Issue 10, 2024
From the journal:

Chemical Communications

Engineering of CdS-chain arrays assembled through S⋯S interactions in 1D semiconductive coordination polymers†

Asuka Nishibe,a   Ryohei Akiyoshi, ORCID logo *a   Akinori Saeki, ORCID logo b   Kazuyoshi Ogasawara, ORCID logo a   Takaaki Tsuruoka ORCID logo c  and  Daisuke Tanaka ORCID logo *a  

* Corresponding authors

a Department of Chemistry, School of Science, Kwansei Gakuin University, 1 Gakuen Uegahara, Sanda, Hyogo 669-1330, Japan
E-mail: r.akiyoshi@kwansei.ac.jp, dtanaka@kwansei.ac.jp

b Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

c Department of Nanobiochemistry, Frontiers of Innovative Research in Science and Technology (FIRST), Konan University, Kobe, Hyogo 650-0047, Japan

Abstract

One-dimensional (1D) Cd(II) coordination polymers [Cd(x-SPhOMe)2]n (x = ortho, meta, and para; HSPhOMe = methoxybenzenethiol) containing inorganic 1D (–Cd–S–)n chains were synthesized. Among these, the KGF-31 polymer bearing para-SPhOMe featured a three-strand chain structure assembled via interchain S⋯S interactions and exhibited high photoconductivity and longevity.

Graphical abstract: Engineering of CdS-chain arrays assembled through S⋯S interactions in 1D semiconductive coordination polymers

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Article information

DOI
https://doi.org/10.1039/D3CC05689A
Article type
Communication
Submitted
20 Nov 2023
Accepted
28 Dec 2023
First published
02 Jan 2024

Chem. Commun., 2024,60, 1277-1280

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Engineering of CdS-chain arrays assembled through S⋯S interactions in 1D semiconductive coordination polymers

A. Nishibe, R. Akiyoshi, A. Saeki, K. Ogasawara, T. Tsuruoka and D. Tanaka, Chem. Commun., 2024, 60, 1277 DOI: 10.1039/D3CC05689A

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