Issue 12, 2024
From the journal:

Chemical Communications

A bromo(boryloxy) silylene and its heavier analogues†

Robin Guthardt ORCID logo *a  and  Cameron Jones ORCID logo *a  

* Corresponding authors

a School of Chemistry, Monash University, Australia
E-mail: cameron.jones@monash.edu

Abstract

A N-heterocylic boryloxy ligand equipped with bulky diazaboryl N-substituents is used to synthesize divalent and dicoordinate group 14 compounds which represent the first examples of acyclic halo(boryloxy) tetrylenes. The bromo(boryloxy) silylene reacts swiftly with benzophenone to a siloxindane.

Graphical abstract: A bromo(boryloxy) silylene and its heavier analogues

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Article information

DOI
https://doi.org/10.1039/D3CC05760G
Article type
Communication
Submitted
24 Nov 2023
Accepted
09 Jan 2024
First published
09 Jan 2024

Chem. Commun., 2024,60, 1583-1586

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A bromo(boryloxy) silylene and its heavier analogues

R. Guthardt and C. Jones, Chem. Commun., 2024, 60, 1583 DOI: 10.1039/D3CC05760G

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