Benzylic amine derivatives are ubiquitous structural motifs in organic chemistry. Herein we report a direct synthesis of these compounds via a direct desulfonylative C-arylation of O-tosyl hydroxamates. The applicability of this Ru-catalyzed aminoalkylation is being exemplified by a set of late-stage functionalizations of natural products.
G. Li, T. Lübken and B. Plietker, Chem. Commun., 2024, 60, 851 DOI: 10.1039/D3CC05825E
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