Issue 14, 2024
From the journal:

Chemical Communications

Geminal bimetallic coordination of a carbone to main-group and transition metals†

Akachukwu D. Obi, ORCID logo a   Chun-Lin Deng,b   Andrew J. Alexis,a   Diane A. Dickie ORCID logo a  and  Robert J. Gilliard, Jr*b  

* Corresponding authors

a Department of Chemistry, University of Virginia, 409 McCormick Road, Charlottesville, Virginia, USA

b Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Building 18-596, Cambridge, MA 02139-4307, USA
E-mail: gilliard@mit.edu

Abstract

The non-bonding carbone lone pair in geometrically-constrained antimony and bismuth carbodiphosphorane complexes readily complexed AuCl to afford rare examples of geminal bimetallic carbone coordination featuring a main-group metal.

Graphical abstract: Geminal bimetallic coordination of a carbone to main-group and transition metals

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Article information

DOI
https://doi.org/10.1039/D3CC06226K
Article type
Communication
Submitted
22 Dec 2023
Accepted
15 Jan 2024
First published
16 Jan 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 1880-1883

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Geminal bimetallic coordination of a carbone to main-group and transition metals

A. D. Obi, C. Deng, A. J. Alexis, D. A. Dickie and R. J. Gilliard, Chem. Commun., 2024, 60, 1880 DOI: 10.1039/D3CC06226K

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