Issue 14, 2024

Geminal bimetallic coordination of a carbone to main-group and transition metals

Abstract

The non-bonding carbone lone pair in geometrically-constrained antimony and bismuth carbodiphosphorane complexes readily complexed AuCl to afford rare examples of geminal bimetallic carbone coordination featuring a main-group metal.

Graphical abstract: Geminal bimetallic coordination of a carbone to main-group and transition metals

Supplementary files

Article information

Article type
Communication
Submitted
22 Dec 2023
Accepted
15 Jan 2024
First published
16 Jan 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 1880-1883

Geminal bimetallic coordination of a carbone to main-group and transition metals

A. D. Obi, C. Deng, A. J. Alexis, D. A. Dickie and R. J. Gilliard, Chem. Commun., 2024, 60, 1880 DOI: 10.1039/D3CC06226K

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