A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds†
Abstract
A N2-bridged tetranuclear Sc(III)–Ni(0) complex featuring a Ni → Sc interaction and a 4-membered [Sc–N–C–Ni] ring was synthesized and characterized. Bimetallic reactivity was demonstrated via reactions with a series of unsaturated compounds containing NC, C
N, C
C, C
O and N
N bonds.