The synthesis, characterization and reactivities of iminoborane radicals were reported. Both X-ray analysis and density functional theory calculations revealed that the unpaired electron delocalizes over the N(1)–C(1)–B(1)–N(2) moiety. Radical trap reactions showed that this radical species acts as a boron radical. These reactions also serve as methods for the synthesis of Lewis base-stabilized oxyl-terminated iminoboranes.
H. Wang, Chem. Commun., 2024, 60, 3806 DOI: 10.1039/D4CC00720D
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