Isolation of a copper photocatalyst on a metal–organic cage for the sulfonylation of aryl halides resulting from visible-light-mediated C(sp2)–S cross-coupling

Lehua Zhao; Yu Zhang; Huali Wang; Jing Wang; Cheng He; Liang Zhao; Chunying Duan

doi:10.1039/D4CC02061H

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Isolation of a copper photocatalyst on a metal–organic cage for the sulfonylation of aryl halides resulting from visible-light-mediated C(sp²)–S cross-coupling†

Lehua Zhao,‡^a Yu Zhang,‡^a Huali Wang,^a Jing Wang,^a Cheng He,

^a Liang Zhao

*^a and Chunying Duan

Author affiliations

* Corresponding authors

^a State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, Dalian University of Technology, Dalian 116024, P. R. China
E-mail: zhaol@dlut.edu.cn

^b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China

Abstract

A Ce-based metal–organic tetrahedron was assembled for preserving the uncoordinated nature of 2,2′-bipyridyl groups to form a Cu-based photocatalyst, which protected Cu^I centers from intermolecular deactivation and showed high photocatalytic activity for the visible-light-mediated C(sp²)−S cross-coupling.

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Article information

DOI: https://doi.org/10.1039/D4CC02061H
Article type: Communication
Submitted: 29 Apr 2024
Accepted: 29 May 2024
First published: 01 Jun 2024

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Chem. Commun., 2024,60, 6805-6808

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Isolation of a copper photocatalyst on a metal–organic cage for the sulfonylation of aryl halides resulting from visible-light-mediated C(sp²)–S cross-coupling

L. Zhao, Y. Zhang, H. Wang, J. Wang, C. He, L. Zhao and C. Duan, Chem. Commun., 2024, 60, 6805 DOI: 10.1039/D4CC02061H

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Chemical Communications