Ebselen (EbSe), a therapeutically significant molecule, is shown to exhibit chalcogen bonding interaction with nitrite anion (ONO−). This report suggests that the σ-holes of EbSe are powerful for offering weak but influential interactions towards biologically relevant ONO−, thereby assisting oxidative transformations like N-nitrosation of aromatic amines.
T. Sahana, A. K. Valappil and S. Kundu, Chem. Commun., 2024, 60, 7725 DOI: 10.1039/D4CC02137A
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