Issue 57, 2024

A bridging bis-phosphanido-phosphinidene complex of lanthanum supported by a sterically encumbering PN ligand

Abstract

Synthesis of a bulky anilidophosphine ligand (short PNTerph) and its lanthanum complexes 1 and 3 is reported. When exposed to KPHMes, both complexes form the first example of a bis-phosphanido-phosphinidene complex 2. This complex undergoes Phospha-Wittig type reactions and its reactivity towards strong bases is further investigated.

Graphical abstract: A bridging bis-phosphanido-phosphinidene complex of lanthanum supported by a sterically encumbering PN ligand

Supplementary files

Article information

Article type
Communication
Submitted
08 May 2024
Accepted
29 May 2024
First published
30 May 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 7299-7302

A bridging bis-phosphanido-phosphinidene complex of lanthanum supported by a sterically encumbering PN ligand

B. Wittwer, F. Heim, K. Wurst and S. Hohloch, Chem. Commun., 2024, 60, 7299 DOI: 10.1039/D4CC02244K

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