Issue 73, 2024
From the journal:

Chemical Communications

A hybrid silylene-Pd catalyst: efficient C–N cross-coupling of sterically bulky amines and chiral amines†

Sandeep H. Kaulage, ORCID logo ‡a   Nasrina Parvin,‡a   Kishor V. Khopadebc  and  Shabana Khan ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Science Education and Research Pune, Dr Homi Bhabha Road, Pashan, Pune-411008, India
E-mail: shabana@iiserpune.ac.in

b Polymer Science and Engineering Division, CSIR-National Chemical Laboratory, Pune, Dr Homi Bhabha Road, Pashan, Pune-411008, India

c Academy of Scientific and Innovative Research (AcSIR), Sector 19, Kamla Nehru Nagar, Ghaziabad 201002, Uttar Pradesh, India

Abstract

Herein, we report a catalytic system with N-heterocyclic silylene (NHSi)-phosphine-based hybrid bidentate ligands [PhC(NtBu)2SiN(PR2)(2,6-iPr2-C6H3)] and Pd(dba)2, which serves as an effective catalyst for C–N cross-coupling of a wide range of sterically bulky amines and optically active amines, which is challenging otherwise.

Graphical abstract: A hybrid silylene-Pd catalyst: efficient C–N cross-coupling of sterically bulky amines and chiral amines

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D4CC03108C
Article type
Communication
Submitted
25 Jun 2024
Accepted
13 Aug 2024
First published
14 Aug 2024

Chem. Commun., 2024,60, 9958-9961

Permissions

Request permissions

A hybrid silylene-Pd catalyst: efficient C–N cross-coupling of sterically bulky amines and chiral amines

S. H. Kaulage, N. Parvin, K. V. Khopade and S. Khan, Chem. Commun., 2024, 60, 9958 DOI: 10.1039/D4CC03108C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements