Issue 76, 2024

(NHC)Ni(ii)-catalyzed regioselective hydroalkenylation of norbornene derivatives: fine-tuning of NHC ligands and donor alkenes

Abstract

This study introduced a novel cross-hydroalkenylation approach for addressing a resilient challenge in C5-exo-selective norbornene derivative functionalization. The process, guided by mutual interactions among the NHC–Ni catalyst and the substrate pairs, ensured highly chemo- and regio-selective insertion.

Graphical abstract: (NHC)Ni(ii)-catalyzed regioselective hydroalkenylation of norbornene derivatives: fine-tuning of NHC ligands and donor alkenes

Supplementary files

Article information

Article type
Communication
Submitted
02 Jul 2024
Accepted
25 Jul 2024
First published
03 Sep 2024

Chem. Commun., 2024,60, 10508-10511

(NHC)Ni(II)-catalyzed regioselective hydroalkenylation of norbornene derivatives: fine-tuning of NHC ligands and donor alkenes

M. Yu, X. Gu and C. Ho, Chem. Commun., 2024, 60, 10508 DOI: 10.1039/D4CC03258F

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