Issue 74, 2024

The electrophilic methylating agent [SO2Me]+ parent of two cationic species

Abstract

Methylfluoride and hydrogen fluoride react with powerful methylating agent [SO2Me]+ in a temperature-dependent addition reaction to form methylated fluorosulfuric acid [FS(OMe)2][Sb2F11] and methylated fluorosulfuric acid methyl ester [FS(OH)(OMe)][SbF6], respectively. The obtained methylated fluorosulfinic acid and methylated fluorosulfinic acid methyl ester were characterized by single X-ray structure analysis and vibrational spectroscopy.

Graphical abstract: The electrophilic methylating agent [SO2Me]+ parent of two cationic species

Supplementary files

Article information

Article type
Communication
Submitted
08 Jul 2024
Accepted
20 Aug 2024
First published
27 Aug 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 10148-10151

The electrophilic methylating agent [SO2Me]+ parent of two cationic species

D. Hollenwäger, V. Bockmair and A. J. Kornath, Chem. Commun., 2024, 60, 10148 DOI: 10.1039/D4CC03400G

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