Chloride leaching/removal is a fundamental reaction of polyvinyl chloride (PVC), pertinent to PVC recycling and environmental impacts. We show that quantum tunnelling (QT) drives >90% of chloride leaching from PVC to water at all environmentally relevant temperatures offering new insights into plastic degradation and transformation processes.
G. Olajide and T. Szilvási, Chem. Commun., 2024, 60, 11924 DOI: 10.1039/D4CC03489A
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