Issue 78, 2024

Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ cage architectures

Abstract

Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bonding-accepting or -donating properties are reported. They showed stimulus-responsive dis- and reassembly, while guest binding was found to be dependent on the complementary properties of the guest to the host in terms of charge, size and H bonding properties.

Graphical abstract: Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ cage architectures

Supplementary files

Article information

Article type
Communication
Submitted
19 Jul 2024
Accepted
30 Aug 2024
First published
30 Aug 2024

Chem. Commun., 2024,60, 10950-10953

Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ cage architectures

H. B. Gearing, T. Söhnel, P. Young, L. Lisboa, L. J. Wright, J. D. Crowley and C. G. Hartinger, Chem. Commun., 2024, 60, 10950 DOI: 10.1039/D4CC03613A

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