Issue 78, 2024
From the journal:

Chemical Communications

Construction of quaternary alkyl motifs through palladium-catalyzed oxidative coupling of 1,3-dicarbonyl compounds with alkenes followed by C–C bond cleavage†

Xu Zhang, ORCID logo *a   Mengfan Chang,a   Tongtong Ni,a   Xuefeng Xu,a   Luyi Zongab  and  Ting Li ORCID logo *a  

* Corresponding authors

a College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang 473061, China
E-mail: zhangxuedu@126.com, chemlt2015@nynu.edu.cn

b Henan Tianguan Group Co., Ltd, China

Abstract

A palladium-catalyzed coupling reaction has been developed for the generation of tertiary alkylation products by reacting olefins with diversely functionalized 1,3-dicarbonyls. The reaction involves the tertiary C–H alkylation of 1,3-dicarbonyls with olefins to produce a tertiary alcohol, followed by C–C bond cleavage.

Graphical abstract: Construction of quaternary alkyl motifs through palladium-catalyzed oxidative coupling of 1,3-dicarbonyl compounds with alkenes followed by C–C bond cleavage

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Article information

DOI
https://doi.org/10.1039/D4CC03676J
Article type
Communication
Submitted
22 Jul 2024
Accepted
02 Sep 2024
First published
03 Sep 2024

Chem. Commun., 2024,60, 10958-10961

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Construction of quaternary alkyl motifs through palladium-catalyzed oxidative coupling of 1,3-dicarbonyl compounds with alkenes followed by C–C bond cleavage

X. Zhang, M. Chang, T. Ni, X. Xu, L. Zong and T. Li, Chem. Commun., 2024, 60, 10958 DOI: 10.1039/D4CC03676J

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